Rapid method for small grain and corn flour authentication using GC/EIMS and multivariate analysis

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dc.contributor.authorPastor, Kristian
dc.contributor.authorAčanski, Marijana
dc.contributor.authorVujić, Đura
dc.contributor.authorBekavac, Goran
dc.contributor.authorMilovac, Snežana
dc.contributor.authorKravić, Snežana
dc.date.accessioned2017-11-21T18:59:52Z
dc.date.available2017-11-21T18:59:52Z
dc.date.issued2016-02
dc.descriptionpeer-revieweden_US
dc.description.abstractThe aim of this study was the application of the gas chromatography–mass spectrometry system (GC/EI–MS) system and multivariate data analysis to investigate the possibility of chemical differentiation between small grain flour (wheat, barley, oat, triticale, rye) and corn flour samples. All cereal flour samples were first defatted with hexane, after which the extraction with ethanol was performed. Extracted simple sugars (monosaccharides, disaccharides, trisaccharides, and sugar alcohols) were analyzed in the form of their corresponding trimethylsilyl oximes. Peaks of simple sugar derivatives were selected in total ion current (TIC) chromatograms by monitoring exclusively the following characteristic abundant ions: 204, 217, and 361 m/z. The total surface areas under the selected peaks were subjected to multivariate analysis. Applying principal coordinate analysis and hierarchical cluster analysis to obtained data, samples of corn flour could be very clearly distinguished from all samples of small grain flour, which presented a weaker separation among each other. This method circumvents common analytical procedures by excluding simple sugar identifications, quantitative analysis, the use of analytical standards, and calibration curves. Results are applicable in the quality assurance of mixed flour on the market, considering the increased popularity of their consumption in human nutrition.en_US
dc.description.sponsorshipThe authors gratefully acknowledge the financial support from the Ministry of Education, Science and Technological Development of the Republic of Serbia (Project TR 31066) and Provincial Secretariat for Science and Technological Development of Vojvodina (Project No. 114-451-1361/2014-03).en_US
dc.identifier.citationK. Pastor, M. Ačanski, Đ. Vujić, G. Bekavac, S. Milovac, S. Kravić. Rapid method for small grain and corn flour authentication using GC/EIMS and multivariate analysis. Food Analytical Methods, 9 (2016) 443–450. DOI: 10.1007/s1216101502156en_US
dc.identifier.issn1936-9751
dc.identifier.urihttp://oa.fins.uns.ac.rs/handle/123456789/37
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/31066/RS//
dc.relation.ispartofseries001;0032
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectGC/EI–MSen_US
dc.subjectSIM modeen_US
dc.subjectmultivariate analysisen_US
dc.subjectcornen_US
dc.subjectsmall grainsen_US
dc.subjectflouren_US
dc.titleRapid method for small grain and corn flour authentication using GC/EIMS and multivariate analysisen_US
dc.title.alternative-en_US
dc.typeinfo:eu-repo/semantics/articleen_US

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